How many hybrid orbitals are present in the molecule PCl5?

Risposta:

There are no atomic hybrid orbitals in "PCl5.

Spiegazione:

A better question might be, "How many hybrid orbitals does a P atom use when it forms a molecule of PCl5?

VSEPR theory predicts that PCl5 should have a trigonal bipyramidal structure, which corresponds to an sp3d ibridazione.

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(Adapted from SlidePlayer)

The P atomo ha cinque orbitali ibridi.

We usually show the P-Cl bond as being formed by the overlap of a phosphorus sp3dorbital with a chlorine 3p orbitale.

sovrapposizione
(Adapted from SlidePlayer)

However, once a PCl bond has formed, the original atomic orbitals no longer exist.

They have become σ molecular orbitals.

Così, la PCl5 molecule has no hybridized atomic orbitals.

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